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投稿时间:2021-03-08 修订日期:2021-03-08
投稿时间:2021-03-08 修订日期:2021-03-08
中文摘要: 废铅膏的成分复杂,其中PbO2比较稳定,难以回收利用。采用硫酸、草酸溶液同步浸出废铅膏,分别探究硫酸浓度、草酸添加量和反应时间对废铅膏硫酸化的影响。结果表明,5 g废铅膏在25 mL质量分数为85%的硫酸、草酸添加量1.5 g,反应时间2.0 h的条件下充分反应,得到的酸浸铅膏PbO2含量为1.39%,PbSO4含量达95.76%。同步还原硫酸化过程将废铅膏绝大部分转化为PbSO4,缩短了废铅膏回收的工艺流程,降低了能耗,后续可更简单且高效地进行脱硫工艺。得到的酸浸铅膏可以通过进一步脱硫后低温焙烧回收氧化铅产品。
Abstract:Composition of waste lead paste is complex, in which PbO2 is relatively stable and difficult to recycle. Sulfuric acid and oxalic acid were used to leach waste lead paste simultaneously. Effects of sulfuric acid concentration, oxalic acid addition and reaction time on sulfation of waste lead paste were investigated. The results show that 5 g waste lead paste is fully reacted under the conditions including 25 mL of 85% sulfuric acid, 1.5 g oxalic acid, and 2.0 h reaction time, respectively. Contents of PbO2 and PbSO4 in acid leaching lead paste are 1.39% and 95.76% respectively. Most of waste lead paste is converted into PbSO4 during simultaneous reduction and sulfation, which will shorten waste lead paste recovery process and reduce energy consumption. The subsequent desulfurization process can be more simple and efficient with this method. The obtained acid leaching lead paste can be recovered in form of lead oxide products by further desulfurization and low temperature roasting.
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基金项目:国家自然科学基金资助项目(21767003)
引用文本:
刘玉玲,黄魁,潘媚媚,董海丽,刘坤捷.废铅膏同步还原硫酸化试验[J].有色金属(冶炼部分),2021(7):7-11.
LIU Yu-ling,HUANG Kui,PAN Mei-mei,DONG Hai-li,Liu Kun-jie.Experiment of Simultaneous Reduction and Sulfation of Waste Lead Paste[J].Nonferrous Metals (Extractive Metallurgy),2021(7):7-11.
刘玉玲,黄魁,潘媚媚,董海丽,刘坤捷.废铅膏同步还原硫酸化试验[J].有色金属(冶炼部分),2021(7):7-11.
LIU Yu-ling,HUANG Kui,PAN Mei-mei,DONG Hai-li,Liu Kun-jie.Experiment of Simultaneous Reduction and Sulfation of Waste Lead Paste[J].Nonferrous Metals (Extractive Metallurgy),2021(7):7-11.