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投稿时间:2021-12-13 修订日期:2021-12-30
投稿时间:2021-12-13 修订日期:2021-12-30
中文摘要: 通过将ZnS纳米粒子负载在阳离子树脂D001中制备负载纳米ZnS阳离子树脂吸附剂,即ZnS@D001,吸附湿法冶金锌浸出液中共存杂质金属离子(如Cu2+和Cd2+)。在10 g/L Zn2+的合成溶液中实现了对Cu2+的高度优先吸附,而对Cd2+没有任何吸附效果。吸附后的ZnS@D001树脂可以被1 mol/L HNO3有效解吸,然后再次负载ZnS。同时利用含有Cu2+和Cd2+的Zn2+溶液进行固定床柱吸附测试。经过吸附处理后,可以有效去除溶液中的铜杂质,纳米ZnS树脂可作为锌冶炼行业深度净化锌液的潜在功能材料。
Abstract:Nano-ZnS loaded cationic resin adsorbent, namely ZnS@D001, was prepared by loading ZnS nanoparticles in cationic resin D001 and used to absorb coexisting impurity metal ions (such as Cu2+ and Cd2+) in hydrometallurgical zinc leaching solution. High priority adsorption of Cu2+ were achieved in 10 g/L Zn2+ synthetic solution, but there was no adsorption effect on Cd2+. The adsorbed ZnS@D001 resin can be effectively desorbed by 1 mol/L HNO3, and then loaded with ZnS again. At the same time, the fixed bed column adsorption of synthetic zinc ion solution containing Cu2+ and Cd2+ metal ion impurities were tested. After treatment, copper impurity content in effluent can be effectively removed, which can be used as a potential functional material for deep purification of zinc liquid in the zinc smelting industry.
keywords: nanoparticles ion exchange resins D001 impurity metal ions Cu2+ Cd2+ Tangnan membrane effect
文章编号: 中图分类号: 文献标志码:
基金项目:国家重点研发计划项目(2019YFC1907403)
作者 | 单位 | |
朱佳俊 | 北京科技大学 | m15842047808@163.com |
修祎帆 | 北京科技大学,冶金与生态工程学院,海淀区学院路30号 | |
孙建刚 | 北京科技大学,冶金与生态工程学院,海淀区学院路30号 | |
黄凯* | 北京科技大学 | khuang@metall.ustb.edu.cn |
引用文本:
朱佳俊,修祎帆,孙建刚,黄凯.负载纳米ZnS阳离子树脂选择性去除浓锌溶液中的痕量级Cu2+和Cd2+[J].有色金属(冶炼部分),2022(5):14-25.
ZHU Jia-jun,XIU Yi-Fan,SUN Jian-gang,HUANG Kai.Selective Removal of Trace Levels of Cu2+ and Cd2+ in Concentrated Zinc Solution with Loaded Nano-ZnS Cationic Resin[J].Nonferrous Metals (Extractive Metallurgy),2022(5):14-25.
朱佳俊,修祎帆,孙建刚,黄凯.负载纳米ZnS阳离子树脂选择性去除浓锌溶液中的痕量级Cu2+和Cd2+[J].有色金属(冶炼部分),2022(5):14-25.
ZHU Jia-jun,XIU Yi-Fan,SUN Jian-gang,HUANG Kai.Selective Removal of Trace Levels of Cu2+ and Cd2+ in Concentrated Zinc Solution with Loaded Nano-ZnS Cationic Resin[J].Nonferrous Metals (Extractive Metallurgy),2022(5):14-25.