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投稿时间:2022-08-21 修订日期:2022-10-04
投稿时间:2022-08-21 修订日期:2022-10-04
中文摘要: 利用超声浸渍法分别制备了MnOx/TiO2和CeOx-MnOx/TiO2低温选择性催化还原(SCR)脱硝催化剂,并对其进行了SEM、EDS、BET及XPS等表征,在此基础上,研究了催化剂的低温SCR脱硝性能,重点考察了Mn负载量及Ce/Mn摩尔比对催化剂性能的影响,结果表明:当Mn负载量为15%时,催化剂具有较高的催化活性;Ce的掺杂有利于催化剂催化活性的提升,当Ce/Mn=0.8时,其催化活性最高,在180℃时达到了97.86%。另外,Ce的掺杂有利于提升催化剂的抗硫抗水特性,但仍有待进一步提升。
Abstract:The MnOx/TiO2 and CeOx-MnOx/TiO2 catalysts for low temperature selective catalytic reduction (SCR) denitrification were synthesized by ultrasonic impregnation method and characterized by SEM, EDS, BET and XPS. On this basis, the low-temperature SCR denitrification performances of the catalysts were studied, and effects of Mn loading amount and Ce/Mn molar ratio on the catalyst performance were investigated. The results show that when Mn loading amount is 15%, the catalyst has high catalytic activity. The doping of Ce is beneficial to improvement of catalytic activity of the catalyst. When Ce/Mn is 0.8, the catalyst has the highest catalytic activity, which reaches 97.86% at 180 ℃. Ce doping is beneficial to improve the sulfur and water resistance of the catalyst, but it still needs to be further improved.
文章编号: 中图分类号: 文献标志码:
基金项目:矿冶科技集团有限公司科研基金重点项目(02-1905)
| 作者 | 单位 | |
| 童震松* | 矿冶科技集团有限公司 | tongzhensong@163.com |
| 赵志龙 | 矿冶科技集团有限公司 |
| Author Name | Affiliation | |
| TONG Zhen-song | Bgrimm | tongzhensong@163.com |
| ZHAO Zhi-long |
引用文本:
童震松,赵志龙.CeOx-MnOx/TiO2低温SCR催化剂的制备及脱硝性能[J].有色金属(冶炼部分),2022(12):84-91.
TONG Zhen-song,ZHAO Zhi-long.Synthesis and Denitrification Performance of CeOx-MnOx/TiO2 Catalysts for Low Temperature SCR[J].Nonferrous Metals (Extractive Metallurgy),2022(12):84-91.
童震松,赵志龙.CeOx-MnOx/TiO2低温SCR催化剂的制备及脱硝性能[J].有色金属(冶炼部分),2022(12):84-91.
TONG Zhen-song,ZHAO Zhi-long.Synthesis and Denitrification Performance of CeOx-MnOx/TiO2 Catalysts for Low Temperature SCR[J].Nonferrous Metals (Extractive Metallurgy),2022(12):84-91.

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