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投稿时间:2023-03-07 修订日期:2023-03-09
投稿时间:2023-03-07 修订日期:2023-03-09
中文摘要: 赤泥中含有大量有价金属铁,可通过还原焙烧—磁选将铁精矿进行回收,但同时会产生部分磁选尾渣难以处理。以不同焙烧温度下的赤泥还原焙烧—磁选尾渣和高炉矿渣为原料,制备了碱激发地聚物灌浆材料(CRT-S)。结果表明,不同焙烧温度下的CRT-S地聚物灌浆料均符合赫谢尔-巴克利(Herschel-Buckley)模型的表达结果,且拟合后的R2均在0.99以上。焙烧温度700 ℃下力学性能最高,此时,流动度为24.5 cm,初凝时间为120 min,终凝时间为380 min,最终泌水率为2.6%,7 d和28 d的抗压强度分别为9.9 MPa和18.6 MPa;三维CT分析结果表明其气孔和裂缝较小,热流演变下其放热速率和最终放热量较高。CRT-S地聚物灌浆料的微观结构呈片层状结构,XRD和FT-IR表明,CRT-S的水化产物主要以C—S—H为主。将赤泥还原焙烧—磁选尾渣应用于地下灌浆工程中,以解决其难以处理的问题,达到赤泥及其还原焙烧—磁选尾渣多角度、分批次、深层次综合利用的目的。
Abstract:Red mud contains a lot of valuable metallic iron, and iron concentrate can be recovered by the process of reduction roasting-magnetic separation, but at the same time, some magnetic separation tailings will be produced which are difficult to treat. Alkali-activated geopolymer grouting material (CRT-S) was prepared from red mud reduction roasting-magnetic separation tailings and blast furnace slag at different roasting temperatures. The results show that the grouting materials of CRT-S geopolymer at different roasting temperatures are in accordance with the expression results of Herschel-Buckley model with R2 of 0.99 above after fitting. The mechanical properties are the highest at roasting temperature of 700 ℃ with the fluidity of 24.5 cm, initial coagulating time of 120 min, final coagulating time of 380 min, final bleeding rate of 2.6%, and compressive strength at 7 d and 28 d of 9.9 MPa and 18.6 MPa, respectively. Three-dimensional CT shows that its pores and cracks are small, and its heat release rate and final heat release amount are high under the evolution of heat flow. The microstructure of CRT-S geopolymer grouting material is lamellar structure. XRD and FT-IR show that the hydration products of CRT-S geopolymer grouting material are mainly C—S—H. Red mud reduction roasting-magnetic separation tailings are applied in underground grouting engineering to solve its difficult problems and achieve the purpose of multi-angle, batch and deep comprehensive utilization of red mud and its reduction roasting-magnetic separation tailings.
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基金项目:广西科技计划项目(桂科AA22068078-4);广西科技重大专项(2022JBGS041)
引用文本:
吴成志,李成,许晔,李中林,陈俊雪,王丁,李义兵.赤泥还原焙烧—磁选尾渣制备地聚物灌浆材料[J].有色金属(冶炼部分),2023(9):58-67.
WU Chengzhi,LI Cheng,XU Ye,LI Zhonglin,CHEN Junxue,WANG Ding,LI Yibing.Properties of Geopolymer Grouting Materials Prepared from Red Mud Reduction Roasting-Magnetic Separation Tailings[J].Nonferrous Metals (Extractive Metallurgy),2023(9):58-67.
吴成志,李成,许晔,李中林,陈俊雪,王丁,李义兵.赤泥还原焙烧—磁选尾渣制备地聚物灌浆材料[J].有色金属(冶炼部分),2023(9):58-67.
WU Chengzhi,LI Cheng,XU Ye,LI Zhonglin,CHEN Junxue,WANG Ding,LI Yibing.Properties of Geopolymer Grouting Materials Prepared from Red Mud Reduction Roasting-Magnetic Separation Tailings[J].Nonferrous Metals (Extractive Metallurgy),2023(9):58-67.

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