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有色金属(冶炼部分):2025,(6):201-209
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典型矿区土壤中镉铅随地表径流迁移特征及数值模拟
李嘉欣1,熊媛2,聂开1,杨卫春1,徐浩3,汪其明3
(1.中南大学 冶金与环境学院,长沙 410083;2.湖南省生态环境事务中心,长沙 410014;3.中电建生态环境集团有限公司,广东 深圳 518102)
Migration Characteristics and Numerical Simulation of Cadmium and Lead in Soil with Surface Runoff in Typical Mining Areas
LI Jiaxin1, XIONG Yuan2, NIE Kai1, YANG Weichun1, XU Hao3, WANG Qiming3
(1. School of Metallurgy and Environment, Central South University, Changsha 410083, China;2. Hunan Provincial Ecological Environment Affairs Center, Changsha 410014, China;3. China Electric Power Construction Ecological Environment Group Co., Ltd., Shenzhen 518102, Guangdong, China)
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投稿时间:2024-12-11    
中文摘要: 为探究典型矿区土壤中镉铅随地表径流迁移特征规律,选择湖南省某铅锌金属矿区的土壤为研究对象,以铅锌多金属尾矿渣为污染源,通过室内模拟降雨试验和数值模拟相结合的方式,探究典型金属矿区土壤中镉(Cd)和铅(Pb)的水平迁移规律。结果表明:降雨强度和土壤坡度对土壤侵蚀量和地表径流总量的影响显著,降雨强度的影响(相关系数为0.737)明显高于土壤坡度的影响(相关系数为0.649)。Cd和Pb主要以颗粒态形式迁移。当降雨强度从40 mm/h增加到120 mm/h时,Cd和Pb在地表径流中的迁移量分别增加了142.61 μg(增幅354.8%)和22 399.75 μg(增幅438.1%);当土壤坡度从5°增加到25°时,Cd和Pb的迁移量分别增加了87.60 μg(增幅191.9%)和9 133.45 μg(增幅78.2%)。采用HYDRUS-2D模型对矿区土壤中Cd、Pb的水平迁移进行的模拟分析表明,土壤饱和导水率对模型输出的影响最显著。水平迁移试验结果与实测数据的对比显示,平均决定系数R2为0.63,平均均方根误差RMSE为0.527。研究结果可为矿区土壤重金属污染预测提供参考依据。
中文关键词: 地表径流  重金属  迁移  HYDRUS模型
Abstract:A metal mining area located in Hunan Province was selected as the research subject with the aim of comprehensively investigating the characteristics of soil surface runoff migration in typical mining areas. Specifically, lead-zinc polymetallic tailings were identified as the primary pollution source for this study. To achieve a thorough exploration of the horizontal migration of cadmium (Cd) and lead (Pb) in the soil of the typical metal mining area, a combination of indoor simulation rainfall experiments and numerical simulations was carried out. In the indoor simulation rainfall experiments, a series of different conditions were set up. For the indoor experiments, various rainfall intensities and soil slopes were considered as key factors. The rainfall intensities range from 40 mm/h to 120 mm/h, and the soil slopes varies from 5° to 25°. During the experiments, the soil samples were collected from the metal mining area in Hunan Province, and the lead-zinc polymetallic tailings were evenly distributed on the soil surface to mimic the actual pollution situation. For the numerical simulations, the HYDRUS-2D model was employed. The model parameters were optimized through a single - parameter sensitivity analysis and parameter inversion process. In the single - parameter sensitivity analysis, different parameters related to soil properties, such as saturated hydraulic conductivity, were adjusted to observe their impacts on the model output. The results reveal several important findings. Firstly, it is clearly demonstrated that both rainfall intensity and soil slope have significant influences on soil erosion and the total amount of surface runoff. Through statistical analysis, it is found that the influence of rainfall intensity, with a correlation coefficient of 0.737, is remarkably higher than that of the soil slope, which has a correlation coefficient of 0.649. Regarding the migration of Cd and Pb, it is determined that they mainly migrate in particulate form within the soil. When the rainfall intensity increases from 40 mm/h to 120 mm/h, the surface runoff migration amounts of Cd and Pb increase by 142.61 μg and 22 399.75 μg respectively. This represents increases of 354.8% for Cd and 438.1% for Pb. Similarly, when the soil slope increases from 5° to 25°, the migration amounts of Cd and Pb increase by 87.60 μg and 9 133.45 μg respectively, with corresponding increases of 191.9% for Cd and 78.2% for Pb. Secondly, the optimized HYDRUS-2D model was used to simulate and analyze the horizontal migration of Cd and Pb in the mining area soil. A comparison was made between the horizontal migration experiment results simulated by the optimized model and the measured data obtained from the indoor experiments. The statistical analysis shows that the average coefficient of determination (R2) is 0.63, and the average root mean square error (RMSE) is 0.527. These results indicate that the HYDRUS-2D model has a relatively high accuracy in simulating the horizontal migration of heavy metals in the mining area soil. In conclusion, this study successfully investigates the characteristics of soil surface runoff migration and the horizontal migration of Cd and Pb in a typical metal mining area through the combination of indoor simulation rainfall experiments and numerical simulations using the HYDRUS-2D model. The findings of this study provide valuable data and insights into the behavior of heavy metals in mining area soils. The model developed in this study can serve as a reliable tool for predicting the horizontal migration of heavy metals in similar mining area soils, which can potentially assist in the development of effective strategies for soil pollution control and environmental protection in metal mining areas. However, further research can be conducted to explore the long-term effects of heavy metal migration in different types of mining area soils under various environmental conditions.
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基金项目:国家自然科学基金资助项目(52274170);湖南省自然科学基金资助项目(2023JJ0065);企业级科技项目(DJ-ZDXM-2023-24)
引用文本:
李嘉欣,熊媛,聂开,杨卫春,徐浩,汪其明.典型矿区土壤中镉铅随地表径流迁移特征及数值模拟[J].有色金属(冶炼部分),2025(6):201-209.
LI Jiaxin,XIONG Yuan,NIE Kai,YANG Weichun,XU Hao,WANG Qiming.Migration Characteristics and Numerical Simulation of Cadmium and Lead in Soil with Surface Runoff in Typical Mining Areas[J].Nonferrous Metals (Extractive Metallurgy),2025(6):201-209.

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