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投稿时间:2025-01-17 网络发布日期:2025-05-30
投稿时间:2025-01-17 网络发布日期:2025-05-30
中文摘要: 生物质作为一种全生命周期零碳排放的可再生碳源,在替代煤炭上具有巨大的潜力。在冶金行业,生物质已经得到了一定的研究与关注,但目前来说被关注得更多的是生物质的燃料属性且集中在钢铁行业。选用稻壳炭作为还原剂,冶炼含镍1.45%、铁24.5%的红土镍矿,与神木半焦对比,讨论了还原剂用量、熔炼温度、保温时间对熔炼效果的影响。结果表明,冷却后的镍铁合金出现明显的偏析现象,熔渣的主要成分为镁橄榄石、顽火辉石和辉石。综合考虑镍铁的品位和回收率,红土镍矿火法冶炼工艺中,稻壳炭作为还原剂可行且效果良好。熔炼过程的最佳参数为:还原剂固定碳质量和红土镍矿中NiO和Fe2O3的氧质量之和比取0.339 kg/kg(神木半焦用量5%,稻壳炭用量6.38%),高温熔分参数取1 550 ℃保温60 min,采用稻壳炭和神木半焦还原获得镍铁合金含铁分别为85.98%、87.31%,含镍分别为12.47%、11.26%。对应镍回收率分别为95.18%、97.00%;铁的回收率分别为77.76%、64.67%。合金中几乎不含锰和铬,钴的回收率则分别为40.8%、37.9%。
Abstract:The metallurgical industry has high coal consumption and large carbon emissions. Biomass, as a renewable carbon source with zero carbon emissions throughout its entire life cycle, has enormous potential in replacing coal. In the metallurgical industry, biomass has received certain research and attention, but currently, more attention is paid to its fuel properties, and mainly concentrated in the steel industry. Nickel is an important strategic metal, currently mainly sourced from nickel laterite ore. Rotary kiln pre-reduction - electric furnace smelting is one of its important smelting methods. In this paper, rice husk char was selected as reductant in the smelting process of nickel laterite ore containing 1.45% nickel and 24.5% iron, with Shenmu semi-coke as the control group. Simulating actual progress, the effects of holding time, holding temperature, and reductant ratio were discussed, and the differences in reducing effect between the two reductants were compared. The experiment was conducted in the QSX-12-17 muffle furnace. About 130 g of nickel laterite ore and a preset ratio of reductant were mixed evenly, covered, and placed in the muffle furnace. The furnace was heated according to the preset heating program. After natural cooling, the crucible was smashed to separate the slag and alloy for detection and analysis. Overall, as the amount of reductant increases, the nickel content in the alloys decreases while the iron content increases, and both recovery rates show an upward trend; The increase in holding temperature and holding time led to an increase in nickel content and recovery rate. The nickel-iron alloys exhibit obvious segregation in each operating condition. The main compositions of the slag are magnesium olivine, enstatite, and pyroxene. Considering the content and recovery rate of nickel and iron, the optimal parameters for the reduction smelting process have been determined as follows: The ratio of fixed carbon mass of reductant to the sum of oxygen mass of NiO and Fe2O3 in laterite nickel ore is 0.339 kg/kg (corresponding to 5% usage of Shenmu semicoke and 6.38% usage of biochar). The melting parameters are set at 1 550 ℃ for 60 minutes, and the alloys, which are reduced by using rice husk charcoal and Shenmu semi coke, each contains iron of 85.98% and 87.31% respectively, and nickel of 12.47% and 11.26% respectively. The corresponding recovery rates are 95.18% and 97.00% for nickel, and 77.76% and 64.67% for iron. The alloys contain almost no manganese and chromium, and contain cobalt of 0.47% and 0.37% respectively. The recovery rates of cobalt are 40.8% and 37.9% respectively for each reductant.
文章编号: 中图分类号: 文献标志码:
基金项目:中国科学院煤炭清洁燃烧与低碳利用战略性先导科技专项资助项目(XDA 29020100)
| 作者 | 单位 |
| 秦国涛 | 中国科学院 工程热物理研究所 煤炭高效低碳利用全国重点实验室,北京 100190;中国科学院大学,北京 100049 |
| 王小芳 | 中国科学院 工程热物理研究所 煤炭高效低碳利用全国重点实验室,北京 100190;中国科学院大学,北京 100049 |
| 郑思奇 | 中国科学院 工程热物理研究所 煤炭高效低碳利用全国重点实验室,北京 100190;中国科学院大学,北京 100049 |
引用文本:
秦国涛,王小芳,郑思奇.生物质炭还原熔炼红土镍矿试验—以神木半焦为对照[J].有色金属(冶炼部分),2025(6):74-82.
QIN Guotao,WANG Xiaofang,ZHENG Siqi.Experimental Study on Reduction Smelting of Nickel Laterite Ore with Biochar: Shenmu Semi-coke as the Control Group[J].Nonferrous Metals (Extractive Metallurgy),2025(6):74-82.
秦国涛,王小芳,郑思奇.生物质炭还原熔炼红土镍矿试验—以神木半焦为对照[J].有色金属(冶炼部分),2025(6):74-82.
QIN Guotao,WANG Xiaofang,ZHENG Siqi.Experimental Study on Reduction Smelting of Nickel Laterite Ore with Biochar: Shenmu Semi-coke as the Control Group[J].Nonferrous Metals (Extractive Metallurgy),2025(6):74-82.

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