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投稿时间:2016-07-29 修订日期:2016-08-05
投稿时间:2016-07-29 修订日期:2016-08-05
中文摘要: 以硫酸为浸出剂,NaCl为沉银剂,对铜阳极泥碱浸渣进行浸出研究,并考察反应温度、硫酸浓度、NaCl添加量、液固比以及反应时间对Cu、Te和Ag浸出效果的影响。结果表明,在H2SO4浓度3 mol/L、NaCl浓度6%、液固比5、反应温度60 ℃、反应时间1.5 h、搅拌速度500 r/min的条件下,Cu、Te和Ag的浸出率分别为92.82%、83.69%和0.21%,实现了贱金属的脱除和贵金属的富集。
Abstract:Alkaline leaching residue of copper anode slime was leached with H2SO4 as leaching agent and NaCl as silver precipitator. The effects of reaction temperature, H2SO4 concentration, NaCl dosage, L/S, and reaction time on leaching of Cu, Te, and Ag were investigated. The results show that leaching rate of Cu, Te, and Ag is 92.82%, 83.69%, and 0.21% respectively under the optimum conditions including H2SO4 concentration of 3 mol/L, NaCl dosage of 6%, L/S=5, reaction temperature of 60 ℃, and leaching time of 1.5 h. Base metals are removed and precious metals are enriched.
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基金项目:2014年湖北省重点产业创新团队项目(鄂组通[2014]36号);湖北省新世纪高层次人才工程专项经费资助项目(鄂人社函[2011]763号);钢铁冶金及资源利用教育部重点实验室开放基金(FMRU201206)
引用文本:
吴星琳,秦庆伟,刘臻伟,王绍宇,王珊,李伟.铜阳极泥碱浸渣中有价金属回收试验[J].有色金属(冶炼部分),2016(12):44-47.
WU Xing-lin,QIN Qing-wei,LIU Zhen-wei,WANG Shao-yu,WANG Shan,LI Wei.Valuable Metals Recovery from Alkaline Leaching Residue of Copper Anode Slime[J].Nonferrous Metals (Extractive Metallurgy),2016(12):44-47.
吴星琳,秦庆伟,刘臻伟,王绍宇,王珊,李伟.铜阳极泥碱浸渣中有价金属回收试验[J].有色金属(冶炼部分),2016(12):44-47.
WU Xing-lin,QIN Qing-wei,LIU Zhen-wei,WANG Shao-yu,WANG Shan,LI Wei.Valuable Metals Recovery from Alkaline Leaching Residue of Copper Anode Slime[J].Nonferrous Metals (Extractive Metallurgy),2016(12):44-47.