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投稿时间:2018-07-06 修订日期:2018-07-06
投稿时间:2018-07-06 修订日期:2018-07-06
中文摘要: 采用正交试验研究硫酸赤泥熟化浸出液中钪的萃取性能,并通过二次反萃制备出钪富集物。结果表明,当P204浓度10%、相比O/A=1/15、萃取时间5 min时,钪萃取率高达99.27%。当反萃剂为2.5 mol/L NaOH溶液、反萃相比O/A=1/1.5、反萃时间10 min、反应温度95 ℃至水相微微沸腾、反萃次数2次时,钪反萃率为98.34%,获得的初步富集物中钪含量为0.86%,可用于进一步制作高纯氧化钪产品。
Abstract:Orthogonal test was applied to investigate extraction performance of scandium in red mud curing leaching solution. Scandium enrichment was prepared by secondary stripping. The results show that scandium extraction rate is 99.27% under the optimum conditions including P204 concentration of 10%, O/A=1/15 and extraction time of 5 min. Stripping rate of Sc with 2.5 mol/L NaOH as stripping agent is 98.34% under the conditions including O/A=1/1.5, stripping time of 10 min, reaction temperature from 95 ℃ to slight boiling of water phase, and stripping frequency of twice. The obtained initial enrichment with Sc content of 0.86% can be used to produce high-purity scandium oxide products.
keywords: red mud extraction orthogonal test scandium pre-enrichment
文章编号: 中图分类号: 文献标志码:
基金项目:中国地质调查局地质大调查项目(12120113086800)
Author Name | Affiliation | |
XU Lu | Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences | csuxl@139.com |
LUO Yuzhi | ||
SHI Guangda |
引用文本:
徐璐,罗宇智,史光大.从赤泥硫酸熟化浸出液中预富集钪[J].有色金属(冶炼部分),2018(11):39-41.
XU Lu,LUO Yuzhi,SHI Guangda.Scandium Pre-enrichment from Red Mud Sulfuric Acid Curing Leaching Solution[J].Nonferrous Metals (Extractive Metallurgy),2018(11):39-41.
徐璐,罗宇智,史光大.从赤泥硫酸熟化浸出液中预富集钪[J].有色金属(冶炼部分),2018(11):39-41.
XU Lu,LUO Yuzhi,SHI Guangda.Scandium Pre-enrichment from Red Mud Sulfuric Acid Curing Leaching Solution[J].Nonferrous Metals (Extractive Metallurgy),2018(11):39-41.