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投稿时间:2025-03-14 修订日期:2025-03-14
投稿时间:2025-03-14 修订日期:2025-03-14
中文摘要: 铝电解槽阴极炭块的完整性对槽寿命至关重要,其在高温、电解质侵蚀等多种因素作用下易出现裂缝、破损等问题,传统检测技术难以捕捉阴极炭块破损的早期特征及动态变化过程。鉴于此,引入声发射检测技术来检测炭块破损过程中产生的声发射信号,对石墨质和石墨化阴极炭块进行单轴加载试验。通过累积AE振铃计数和轴向刚度分析确定裂纹闭合应力σ_cc、起裂应力σ_ci、损伤应力σ_cd和峰值应力σ_cp的应力阈值。基于这些应力阈值,将炭块破损过程划分为压密阶段、弹性阶段、裂纹稳定扩展阶段和不稳定扩展阶段等四个阶段。同时,对各阶段的声发射参数信号特征进行了研究,揭示了不同破损阶段的声发射参数演化规律。研究表明:1)阴极炭块的声发射b值在裂纹稳定扩展阶段和不稳定扩展阶段长时间处于低位小幅度波动,这表明炭块在失稳破损过程中,裂纹发展速率较为平稳。2)在炭块损伤过程中,石墨化阴极炭块的声发射S值比石墨质阴极炭块更低,这表明石墨质炭块内部裂纹的扩展速率更为剧烈。当S值长时间处于中高位时,预示着阴极炭块破损可能产生。3)基于RA-AF统计的各应力阶段的张剪裂纹占比结果表明,剪切裂纹占比上升是阴极炭块趋近破损的前兆特征。
Abstract:The integrity of cathode carbon block in aluminum electrolysis cell is crucial to the life of the cell, and it is prone to cracks and damages under the action of high temperature, electrolyte erosion and other factors, and it is difficult for traditional inspection techniques to capture the early characteristics of cathode carbon block damages and the dynamic change process. In view of this, the acoustic emission detection technology was introduced to detect the acoustic emission signals generated in the process of carbon block breakage, and uniaxial loading tests were carried out on graphite and graphitized cathode carbon blocks. The stress thresholds for crack closure stress σ_cc, crack initiation stress σ_ci, damage stress σ_cd and peak stress σ_cp were determined by cumulative AE ringing counts and axial stiffness analysis. Based on these stress thresholds, the damage process of cathode carbon block is divided into four stages, including the compaction stage, elasticity stage, stable crack growth stage and unstable crack growth stage. Meanwhile, the acoustic emission parameter signal characteristics of each stage were systematically investigated to reveal the acoustic emission response laws of different breakage stages. The study shows that: 1) The acoustic emission b value of the cathode carbon block is at a low level with small fluctuation for a long time in the stable crack growth stage and unstable crack growth stage, which indicates that the crack development rate of the carbon block is relatively smooth during the destabilized breakage process. 2) The acoustic emission S value of the graphitized cathode carbon block is lower than that of the graphite cathode carbon block in the process of the damage of the carbon block, which indicates that the expansion rate of the cracks within the graphite cathode carbon block is more drastic. When the S value is in the middle-high level for a long time, it indicates that cathode carbon block breakage may occur. 3) The results of tension-shear crack percentage for each stress stage based on RA-AF statistics show that the increase in shear crack percentage is a precursor feature of cathode carbon block approaching breakage.
keywords: aluminum electrolyzer cathode acoustic emission graphite cathode stage characterization fracture mode
文章编号: 中图分类号: 文献标志码:
基金项目:国家自然科学基金资助项目(52274350)
作者 | 单位 | |
温丹辉 | 江西理工大学 冶金工程学院 | 18879746029@163.com |
詹宁宁 | 万基控股集团有限公司 | |
张亚楠 | 中铝郑州有色金属研究院有限公司 | |
吴军 | 中铝郑州有色金属研究院有限公司 | |
张阳 | 中国铝业股份有限公司连城分公司 | |
刘庆生* | 江西理工大学 冶金工程学院 | lqs_01259@126.com |
刘建国 | 万基控股集团有限公司 | |
陈善永 | 包头铝业有限公司 |
引用文本:
温丹辉,詹宁宁,张亚楠,吴军,张阳,刘庆生,刘建国,陈善永.单轴压缩下铝电解槽阴极炭块的声发射阶段特征及微裂纹演化模式[J].有色金属(冶炼部分),2025(5):43-52.
WEN Danhui,ZHAN Ningning,ZHANG Yanan,WU Jun,ZHANG Yang,LIU Qingsheng,LIU Jianguo,CHEN Shanyong.Characteristics of Acoustic Emission Stages and Microcrack Evolution Patterns of Cathode Carbon Blocks in Aluminum Electrolysis Cells under Uniaxial Compression[J].Nonferrous Metals (Extractive Metallurgy),2025(5):43-52.
温丹辉,詹宁宁,张亚楠,吴军,张阳,刘庆生,刘建国,陈善永.单轴压缩下铝电解槽阴极炭块的声发射阶段特征及微裂纹演化模式[J].有色金属(冶炼部分),2025(5):43-52.
WEN Danhui,ZHAN Ningning,ZHANG Yanan,WU Jun,ZHANG Yang,LIU Qingsheng,LIU Jianguo,CHEN Shanyong.Characteristics of Acoustic Emission Stages and Microcrack Evolution Patterns of Cathode Carbon Blocks in Aluminum Electrolysis Cells under Uniaxial Compression[J].Nonferrous Metals (Extractive Metallurgy),2025(5):43-52.