The Crystallization Mechanism of Si Ion in KCl-NaCl-NaF-SiO2 Molten Salt
Received:March 25, 2010            
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DOI:DOI:10.3969/j.issn.1007-7545.2011.03.005
KeyWord:SiO2; KCl-NaCl-NaF; Cyclic voltammetry; Chronoamperometry
        
AuthorInstitution
HE Xiao-feng 河北理工大学
LI Yun-gang 河北理工大学
LI Zhi-hui 河北理工大学
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Abstract:
      Pt as reference and reseach electrode, high pure graphite crucible as assistant electrode, the crystallization mechanism of Si ion on Pt electrode was investigated in KCl-NaCl-NaF-SiO2 molten salt by using cyclic voltammetry and chronoamperometry. The results indicated that process of Si crystallization was hemispheric tridimensional crystal nucleus and continuous growing procedure; the density of crystal nucleus could be increased and good sedimentary formation could be obtained if excessive potential was properly increased.
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