Electrochemical Dissolution Behavior of TiCxO1-x in LiCl-KCl Melt at 450 ℃
Received:October 18, 2010            
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DOI:DOI:10.3969/j.issn.1007-7545.2011.04.005
KeyWord:TiCxO1-x solid solution;LiCl-KCl melt system;Electrochemical dissolution
        
AuthorInstitution
NING Xiao-hui 北京科技大学冶金与生态工程学院
JIAO Shu-qiang 北京科技大学冶金与生态工程学院
ZHU Hong-min 北京科技大学冶金与生态工程学院
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Abstract:
      The anodic dissolution behavior of conductive titanium oxycarbide (TiCxO1-x) in LiCl-KCl melt in 450 ℃ was investigated in detail. A series of experiments were carried out by applying electrochemical methods and mass spectra. The results showed that TiCxO1-x can dissolve in alkali chloride melt. During the anodic dissolution, titanium component of TiCxO1-x dissolves as Ti2+ ion into the molten salt, and the components of carbon and oxygen form carbon monoxide (CO) simultaneously.
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