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| AN ANALYTICAL EVALVATION OF THE ACTIVITIES OF COMPONENTS IN AL-Si-Fe TERNARY ALLOY |
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| DOI:doi:10.3969/j.issn.1007-7545.年份.期号.顺序号 |
| KeyWord:Al-Si-Fe ternary alloy activity analytiacl evaluation |
| Tang Kai,Xu JianLun,Ding Weizhong,Jiang Guochang |
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| Abstract: |
| Expressing the partial molar excess Gibbs energy of component Al in Al-Si-Fe ternary alloy as a polynomial, then the coefficients A jk involved in the polynomial were determined based on the experimental date in ternary system and three selected binary subsystems through a least-squares technique. The coefficients F jk contained in the polynomial of excess molar free energy of alloy were drawn in the light of Gibbs-Duhem equation. The partial molar excss Gibbs energy for the components Si and Fe can be calculated by use of the coefficients A jk and F jk through a modified "I-D" approach. In present analytical model, the iso-activity lines of three component in the Al-Si-Fe ternary alloy were calculated in the whole homogeneous region. |
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