Effect of Liquid-Liquid Structure Transition on Solidification and Microstructure of CuSn Alloys
Received:March 30, 2011            
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DOI:DOI:10.3969/j.issn.1007-7545.2011.09.010
KeyWord:CuSn30 Alloy; Liquid-Liquid Structure Transition; Superheat Treatment; Solidification behavior
           
AuthorInstitution
XI Yun 合肥工业大学 工业培训中心
CHEN Zhi-hao 安徽工程科技学院有色金属材料省级试验室
ZHU Xie-bing 安徽工程科技学院有色金属材料省级试验室
ZU Fang-qiu 合肥工业大学 工业培训中心
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Abstract:
      An abnormal irreversible change was found on ρ-T and DSC curves of liquid CuSn30% alloy, which suggested a liquid structural transition occurring in the melt. In the interval before and after, the effect of the structure change on solidification behavior and solidified structure were studied through superheat treatment. The results indicated that the irreversible structure change could lead to higher supercooling degree during solidification, and the primary phase and eutectoid phase became finer and more dispersive. The mechanism of above phenomena was also discussed briefly.
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