Theoretical Research on Material Equilibrium in Polysulfide Solution System
Received:March 24, 2012   Revised:March 26, 2012   Accepted:March 28, 2012      Published Online:September 19, 2012
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DOI:10.3969/j.issn.1007-7545.2012.10.005
KeyWord:nickel electrolysis; polysulfide system; solution; material equilibrium; thermodynamic
     
AuthorInstitution
WEI Daijin 江西省环境保护科学研究院
chen shuai hua 江西科技师范学院化学化工学院
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Abstract:
      As a complex system, polysulfide solution had many kinds of sulfide materials including S2-, S22-, S32-, S42-, S52-, HS-, H2S and S2O32-, HS2O3-, H2S2O3, S4O62-, S5O62-, S2O42-, HS2O4-, S3O62- etc. The distribution equilibrium of these materials in polysulfide system were obtained with thermodynamic calculation based on their chemical reactions and referred the leaching results of de-copper residue slag by sodium sulfide.
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