Study on Cobalt and Aluminum Leaching Process from Spent Lithium Ion Batteries Cathode Materials
Received:September 12, 2012   Revised:September 14, 2012   Accepted:September 17, 2012      Published Online:February 19, 2013
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DOI:10.3969/j.issn.1007-7545.2013.03.004
KeyWord:spent Li-ion battery; thermodynamics; leaching cobalt and aluminum; hydrogen peroxide
              
AuthorInstitution
YIN Xiaoying 中南大学化学化工学院
MAN Ruilin 中南大学化学化工学院
ZHAO Pengfei 中国恩菲工程技术有限公司
CHANG Wei 中南大学化学化工学院
XU Xiaoqun 中南大学化学化工学院
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Abstract:
      Through calculation of basic thermodynamics data and drawing of E-pH diagram of reaction system, the leaching process of recovery of cobalt and aluminum from spent lithium ion battery cathode materials was carried out. The effects of sulfuric acid concentration, leaching time, leaching temperature, hydrogen peroxide dosage and ratio of solid to liquid (L/S) on leaching rate of cobalt and aluminum were investigated. The results show that under the conditions including 273 K, -0.277
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