Study on Cobalt Leaching in Co (Ⅲ)-Na2SO3-H2SO4 System
Received:September 24, 2012   Revised:September 26, 2012   Accepted:September 28, 2012      Published Online:April 23, 2013
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DOI:10.3969/j.issn.1007-7545.2013.05.005
KeyWord:cobalt; concentrated sulfuric acid; leaching rate; filtering performance; polyacrylamide
              
AuthorInstitution
LU Sujun 金川镍钴研究设计院
WANG Shuyou 金川镍钴研究设计院
ZHUGE Fuyu 金川镍钴研究设计院
ZHANG Han 金川镍钴研究设计院
ZHANG Peng 金川镍钴研究设计院
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Abstract:
      Cobalt-bearing raw materials were reduction leached in sulfuric acid system. The effects of dosage of sulfuric acid and sodium sulfite, leaching temperature, dosage of polyacrylamide on leaching rate of cobalt and the filtering performance were investigated. The results show that the leaching rate of cobalt is above 97% and the filtering performance is favorable under the optimum conditions including (for 1 kg raw materials) ratio of liquid to solid of 5∶1, leaching temperature of 60 ℃, dosage of concentrated sulfuric acid of 400 mL, dosage of sodium sulfite of 360 g, dosage of polyacrylamide of 20~40 mL, and pH value of terminal of 1.0~1.5.
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