Extraction of Calcium from Copper Sulfate Solution with P204
Received:November 13, 2012   Revised:November 13, 2012   Accepted:November 14, 2012      Published Online:April 23, 2013
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DOI:10.3969/j.issn.1007-7545.2013.05.004
KeyWord:P204; extraction; separation of copper and calcium; countercurrent extraction; copper sulfate solution
              
AuthorInstitution
ZhuJun 西安建筑科技大学冶金工程学院
XuWanxiang 西安建筑科技大学冶金工程学院
HonTao 西安建筑科技大学冶金工程学院
LiZhiren 西安建筑科技大学冶金工程学院
ZhuoWen 金川公司铜盐厂
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Abstract:
      P204 was chosen to extract calcium from copper sulfate solution, taking high calcium of impurities in copper sulfate products into consideration. The effects of P204 mass concentration, O/A, extraction time, and equilibrium pH value of aqueous phase on separation of copper and calcium were investigated. The results show that the optimum conditions of P204 extraction include P204 mass concentration of 0.9 mol/L, O/A=5∶1, oscillation time of 3 min, and pH value of 1.5. The calcium mass concentration in water phase is below 5 mg/L after 4-stage countercurrent extraction.
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