Study on Rhenium Separation from In-Situ Leaching Uranium Solution with D302-Ⅱ Resin
Received:January 05, 2013   Revised:January 05, 2013   Accepted:January 06, 2013      Published Online:June 19, 2013
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DOI:10.3969/j.issn.1007-7545.2013.07.012
KeyWord:rhenium; D302-Ⅱ resin; in-situ leaching uranium; adsorption; separation
                 
AuthorInstitution
JIANG Xiao-hui 新疆中核天山铀业公司
LOU Ming-biao 东华理工大学
CHEN Guo-zhen 新疆中核天山铀业公司
HUA Rong 东华理工大学
SONG Jin-ru 东华理工大学
ZHANG Ling 新疆中核天山铀业公司
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Abstract:
      Low concentration rhenium from in-situ leaching uranium solution was separated with weakly basic D302-II resin. The results show that the separation coefficient of rhenium and uranium reaches maximum value of 7 965 in pH 2.0, and the absorption rate still reaches 94.35% when mass ratio of uranium to rhenium is 100∶1, which indicates that uranium in in-situ leaching uranium solution has no interference on adsorption and desorption of rhenium. 62.5 mg rhenium can be adsorbed in per gram D302-II resin, and rhenium concentration in stripping solution is 4.5 mg/mL desorbed from D302-II resin by 250 mL 3 mol/L NH4OH solution. White crystal NH4ReO4 can be obtained from stripping solution after evaporation and concentration
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