Study on Sorption Mechanism of D418 Amino Methylene Phosphonic Acid Resin from Mixed Solution of Thulium, Ytterbium, Lutetium
Received:August 09, 2013   Revised:August 14, 2013   Accepted:August 15, 2013      Published Online:January 20, 2014
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DOI:10.3969/j.issn.1007-7545.2014.02.011
KeyWord:D418 amino methylene phosphonic acid resin; Tm; Yb; Lu; sorption mechanism
        
AuthorInstitution
Jiao YunFen 江西理工大学冶金与化学工程学院
He XiaoLin 上杭赣闽有色金属实业发展有限公司
Jiang Pingguo 江西理工大学冶金与化学工程学院
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Abstract:
      The molar coordination ratio of complex formed by sorption of amino methylene phosphonic acid resin from mixed solution of thulium, ytterbium, lutetium was determined as 1.5∶1 through saturation volumetric method, equimolar series method and slope method. The absorption mechanisms include single molecular and double molecular chelate coordination. Based on IR spectrometry, the preliminary analysis indicates that nitrogen, oxygen atoms in functional group of APAR coordinate with Tm-Yb-Lu ion to form bonding and coordination compound.
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