Effect of Electromagnetic Field on Preparation of Al-Mg Master Alloy by Rotating Liquid Aluminium Cathode Method
Received:April 14, 2014   Revised:April 17, 2014   Accepted:April 18, 2014      Published Online:September 19, 2014
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DOI:10.3969/j.issn.1007-7545.2014.10.015
KeyWord:Al-Mg alloy; Rotating Liquid Aluminium Cathode; back electrodynamic potential; current efficiency
                 
AuthorInstitution
WANG Yi-yong 辽宁科技大学 辽宁省化学冶金工程重点实验室 鞍山
JIN Hu 辽宁科技大学 辽宁省化学冶金工程重点实验室 鞍山
LI Ji-dong 辽宁科技大学 辽宁省化学冶金工程重点实验室 鞍山
ZHANG Jun-wei 辽宁科技大学 激光先进制造技术研发中心 鞍山
Su Jian-ming 辽宁科技大学 激光先进制造技术研发中心 鞍山
Han Chu-fei 辽宁科技大学 辽宁省化学冶金工程重点实验室 鞍山
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Abstract:
      Al-Mg master alloy was prepared by Rotating Liquid Aluminium Cathode Method in Na3PO3-MgF2 molten salt system with MgO as raw material. The technological parameters such as back electrodynamic potential, current intensity, and magnetic field intensity were measured by testing device of molten salt electrolysis and Teslameter. The microstructure of alloy was analyzed by SEM and XRD. The change rules of back electrodynamic potential, current efficiency and magnesium concentration in alloy during preparation were discussed. The results show that alloying of Rotating Liquid Aluminium Cathode can effectively reduce back electrodynamic potential and increase current efficiency and magnesium concentration in alloy. The Al-Mg alloy with Mg 24.5% can be obtained by electrolyzing for 3 h at current intensity of 5 A and 950 ℃ with current efficiency of 83%. The alloy has dense crystal structure and homogeneous distribution of elements with phase of Al12Mg17.
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