Purification Technology for Arsenic-bearing Sodium Hydroxide
Received:July 21, 2014   Revised:July 31, 2014   Accepted:August 01, 2014      Published Online:November 19, 2014
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DOI:10.3969/j.issn.1007-7545.2014.12.010
KeyWord:arsenic-bearing sodium hydroxide; arsenic removal; barium hydroxide; purification
              
AuthorInstitution
JIN Cheng-yong 湖南锡矿山闪星锑业有限责任公司
LIAO Guang-rong 湖南锡矿山闪星锑业有限责任公司
SHAN Tao-yun 湖南锡矿山闪星锑业有限责任公司
deng wei hua 锡矿山闪星锑业有限责任公司
LIU Que-ming 湖南锡矿山闪星锑业有限责任公司
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Abstract:
      Arsenic-bearing sodium hydroxide solution was purified to prepare solidity sodium hydroxide with ≤0.05% As and 92%~96% NaOH by processes of oxidation de-antimony, removal of carbonate, sulfate and some arsenic with lime milk, deeply de-arsenic with barium hydroxide, purification with ferric sulfate, and concentration. Total arsenic removal rate is 99.70% above. This process has advantages of short flowsheet and simple operation. Purification and recycling of sodium hydroxide solution bearing with 1~5 g/L arsenic is realized.
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