Thermodynamic Optimization of MNO3-Ca(NO3)2(M=Li, Na, K) Binary System
Received:October 29, 2014   Revised:November 03, 2014   Accepted:November 04, 2014      Published Online:March 23, 2015
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DOI:10.3969/j.issn.1007-7545.2015.04.003
KeyWord:phase diagram; thermodynamic; optimization; Gibbbs energy; Ca(NO3)2
           
AuthorInstitution
XU Fang 湖北科技学院
WANG Jun-tao 湖北科技学院
LAI Meng-ze 中南大学
CHEN Jing 中国科学院
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Abstract:
      Melting Gibbbs energy of Ca(NO3)2 and a consistent set of thermodynamic parameters were optimized by CALPHAD method for MNO3-Ca(NO3)2(M=Li, Na, K) binary system, which was for the first time thermo-dynamically assessed. Phase diagrams of MNO3-Ca(NO3)2(M=Li, Na, K) binary system were calculated with the model parameters obtained in this study. Comparison of calculated and experimental phase diagram data was carried out.
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