Study on Palladium Removal from Silver Electrolyte by Sodium Butyl Xanthate
Received:November 09, 2015  Revised:November 09, 2015
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DOI:doi:10.3969/j.issn.1007-7545.2016.05.009
KeyWord:sodium butyl xanthate; silver electrolyte; palladium; recovery
                 
AuthorInstitution
SEN Wei 云南锡业集团(控股)有限责任公司
YANG Ji-sheng 云南锡业集团(控股)有限责任公司
YANG De-xiang 云南锡业集团(控股)有限责任公司
BAI Jia-fu 云南锡业集团(控股)有限责任公司
MA Zi-hui 云南锡业集团(控股)有限责任公司
LIN Da-zhi 云南锡业集团(控股)有限责任公司
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Abstract:
      Palladium was precipitated from palladium-bearing silver electrolyte by sodium butyl xanthate (SBX). Silver was electrolyzed from palladium-precipitated electrolyte. The results show that palladium can be efficiently enriched from silver electrolyte by SBX. Palladium precipitation rate is 99.84% and palladium content in palladium concentrate is 12.19% under the optimum conditions including SBX dosage of 3.6 times of palladium content, reaction temperature of 70 ℃, and time of 1 h. Silver powder meeting standard of IC-Ag99.99 is obtained by electrolysis from palladium-precipitated electrolyte.
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