Thermodynamic Analysis on One-step Synthesis Ti-Al-xFe-ySi Multielement Alloy by Aluminothermic Reduction
Received:January 28, 2016  Revised:February 01, 2016
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DOI:doi:10.3969/j.issn.1007-7545.2016.07.015
KeyWord:titanium slag; aluminothermic reduction; thermodynamics; Ti-Al-xFe-ySi alloy
                          
AuthorInstitution
Jun Li 上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室
XiongGangLu 上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室
ShaoliYang 攀枝花学院 攀西科技创新中心
ChongheLi 上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室
EnHuiWu 攀枝花学院 攀西科技创新中心
JingHou 攀枝花学院 攀西科技创新中心
Pinghuang 攀枝花学院 攀西科技创新中心
BinBinLi 攀枝花学院 攀西科技创新中心
WangTao 攀枝花学院 攀西科技创新中心
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Abstract:
      The feasibility to produce Ti-Al-xFe-ySi mutielement alloy from titanium slag by aluminothermic reduction was theoretically analyzed. Possible chemical reactions between metallic oxide in titanium slag and aluminum were calculated and analyzed. The priority reduction degree of metallic oxide was discussed. The results show that it is feasible to produce Ti-Al-xFe-ySi mutielement alloy from titanium slag by aluminothermic reduction. Main binary alloy phase presents as Ti5Si3, TiAl3, and TiFe from thermodynamics analysis and validated by experiments. Main phases of prepared alloy include Al2.68Mn0.32Ti and Al3Ti0.75Fe0.25, and a small amount of TiFe and Ti3SiC2.
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