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Hydrometallurgical Process to Recover Manganese Carbonate from Manganese Oxide Ore Tailings |
Received:December 28, 2016 Revised:December 30, 2016 |
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DOI:doi:10.3969/j.issn.1007-7545.2017.05.004 |
KeyWord:manganese oxide ore tailings; sulfur dioxide; reduction leaching; manganese carbonate |
Author | Institution |
ZHANG Li-qiang |
郑州职业技术学院电气系 |
ZHANG Xiu-feng |
中国地质科学院郑州矿产综合利用研究所 |
HUANG Jing-wei |
中国地质科学院郑州矿产综合利用研究所 |
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Abstract: |
Manganese oxide ore tailings were leached by SO2 in sulfuric acid solution. Lixivium was purified and reacted with ammonium bicarbonate to recover manganese carbonate. Under the optimum conditions, manganese leaching rate is 96% above, removal rate of Fe, Al, and Si is 100%, 99.6%, and 96.9% respectively with the optimum pH value of 5.2 adjusted by ammonia addition. Manganese precipitation rate is 99.8%. Total manganese recovery rate is 90.5%. MnCO3 product meets the requirement of the first grade of Standard HG/T4203-2011 Industrial Manganese Carbonate. |
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