Arsenic Removal from Copper Smelting Ash Assisted by Microwave and Oxidation
Received:January 16, 2017   Revised:January 18, 2017   Accepted:January 20, 2017      Published Online:April 20, 2017
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DOI:doi:10.3969/j.issn.1007-7545.2017.05.002
KeyWord:copper smelting dust; microwave; selectivity; separation; arsenic; oxidation; leaching
              
AuthorInstitution
wangqian 催化材料科学国家民委-教育部共建重点实验室
Guo Li 中国地质大学(武汉)
Chen Shaohua 催化材料科学国家民委-教育部共建重点实验室
Song Ziyu 催化材料科学国家民委-教育部共建重点实验室
Du Dongyun 催化材料科学国家民委-教育部共建重点实验室
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Abstract:
      Copper smelting dust (referred to as “soot”) was investigated through Na2S-NaOH leaching process assisted with microwave and oxidation. The results show that leaching rate of As, Cu, Zn, and Pb is 98.45%, 3.64%, 3.88%, and 0.41% respectively under the optimum conditions including microwave time of 180 s, microwave gear of 7 (560 W), and oxygen flux of 10 L/min. Arsenic is selectively separated from soot. Na2S-NaOH leaching assisted with microwave and oxidation is an efficient way to remove arsenic from soot based on XPS, XRD, SEM, and speciation analysis of heavy metals.
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