Technical Research on Chlorine Reduction in Promethium-Neodymium Oxide
Received:February 16, 2017  Revised:February 20, 2017
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DOI:doi:10.3969/j.issn.1007-7545.2017.06.013
KeyWord:low chlorine; promethium-neodymium carbonate; promethium-neodymium oxide
        
AuthorInstitution
ZHANG Yong-hua 内蒙古科技大学 材料与冶金学院
WU Jin-xiu 内蒙古科技大学 材料与冶金学院
GUO Xiao-hui 内蒙古科技大学 材料与冶金学院
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Abstract:
      Chloride in promethium-neodymium oxide after precipitation and burning of promethium-neodymium chloride was high. Effects of settling time and concentration of feed liquid of two precipitation processes, temperature, loading mode, and ventilation rate in calcination process on content of chlorine root were investigated. The results show that with cocurrent flow process, content of chlorine root in promethium-neodymium carbonate and promethium-neodymium oxide is 0.035% below and 0.010% below respectively under the conditions including feed liquid concentration of 180 g/L, precipitation time of >6 h, calcination temperature of 1 050 ℃, charging loose, and ventilation rate of per ton REO of 150 m3/min. Crystal morphology of carbonate and oxide exerts some effect on content of chlorine root based on SEM analysis.
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