Preparation of Ti-Al-xFe-ySi Alloy from Electro-titanium Slag by Electro-Aluminothermic Reduction
Received:March 24, 2017   Revised:March 28, 2017   Accepted:March 29, 2017      Published Online:July 17, 2017
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DOI:doi:10.3969/j.issn.1007-7545.2017.08.007
KeyWord:electro-titanium slag; electro-aluminothermic reduction; Ti-Al-xFe-ySi alloy
                          
AuthorInstitution
LI Jun 上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室
LU Xiong-Gang 上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室
YANG Shao-Li 攀枝花学院
Ma Lan 攀枝花学院
WU En-Hui 攀枝花学院
HOU Jing 攀枝花学院
LI Chong-He 上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室
Wang Tao 攀枝花学院
Li Bin-Bin 上海大学 省部共建高品质特殊钢冶金与制备国家重点实验室;攀枝花学院
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Abstract:
      Ti-Al-xFe-ySi alloy was synthesized from electro-titanium slag in Panzhihua by electro-aluminothermic reduction. Effect of CaO addition on slag-gold separation, alloy yield, and titanium yield was investigated. With CaO/Al of 1.1, low melting point phases such as Al2O3?CaO and 7Al2O3?12CaO are mainly produced from reduction slag, and yield of alloy and Ti is 62% and 92% respectively with oxygen content in alloy of 1.32%. Main phase of alloy is composed of TiAl3 and TiAl, Fe in slag replaces Ti in TiAl3 to form Al3Ti0.75Fe0.25, and Si is mainly combined with Ti in alloy to form Ti5Si3. Small amount of C in alloy combines with TiAl and TiSi to form new phase of Ti3SiC2 and Ti2AlC.
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