Treatment of Low Grade Vanadium-Bearing Titanomagnetite Concentrates by Direct Reduction
Received:April 05, 2017   Revised:April 20, 2017   Accepted:April 21, 2017      Published Online:August 21, 2017
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DOI:doi:10.3969/j.issn.1007-7545.2017.09.013
KeyWord:low grade vanadium-bearing titanomagnetite concentrates; direct reduction; metallization ratio; separation
                       
AuthorInstitution
BAI Yun 昆明理工大学冶金与能源工程学院
CHEN De-sheng 中国科学院过程工程研究所
MA Wen-hui 昆明理工大学冶金与能源工程学院
WANG Li-na 中国科学院过程工程研究所
ZHAO Hong-xin 中国科学院过程工程研究所
ZHEN Yu-lan 中国科学院过程工程研究所
YU Hong-dong 中国科学院过程工程研究所
QI Tao 中国科学院过程工程研究所
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Abstract:
      Low grade vanadium-bearing titanomagnetite concentrates were reduced isothermally with addition of a small amount of Na2CO3 NaCl at 1 000~1 300 ℃ and anthracite as reductant. Iron concentrates and vanadium-bearing titanium slag were obtained by magnetic separation. The effects of C/Fe molar ratio, reduction temperature, and reduction time on metallization degree of iron, content of V/Ti in samples, and phase transformation were investigated. The results show that C/Fe molar ratio and reduction temperature have great impacts on direct reduction process. Metallization degree is 92.8% under the conditions including C/Fe molar ratio of 1.2, reduction temperature of 1 200 ℃, and reduction time of 2 h. Vanadium is enriched in titanium slag after reduction. Efficient separation between Fe and V/Ti is achieved.
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