Recovery of Cathode Material from Spent LiCoO2 Materials with Triethanolamine
Received:May 22, 2017   Revised:June 15, 2017   Accepted:June 15, 2017      Published Online:September 18, 2017
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DOI:doi:10.3969/j.issn.1007-7545.2017.10.016
KeyWord:spent LiCoO2 materials; cathode material; triethanolamine; hydro-extraction; recycle
           
AuthorInstitution
Gao yan 河南省冶金研究所有限责任公司
XU Xiao-ju 河南省冶金研究所有限责任公司
Li Jin-hui 江西理工大学 冶金与化学工程学院
Chan Shi-qiang 河南省冶金研究所有限责任公司
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Abstract:
      Process to recycle lithium cobalt oxide cathode material directly from scrap of cobalt-aluminium film was investigated. The results show that 81% of lithium cobalt oxide cathode material can be recovered under the conditions including reaction temperature of 50 ℃, reaction time of 2 h, triethanolamine concentration of 0.5 mol/L, ratio of solid to liquid of 0.75/10, and ultrasonic frequency of 18 kHz. The process exerts much fewer damaging effects on lithium cobalt oxide than other strong acid system. With little change on structure and morphology, lithium cobalt oxide can be recycled directly to produce lithium battery.
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