Study on Primary Crystallization Temperature of NaCl-KCl-NaF-Fe3O4 Molten Salt
Received:January 14, 2018   Revised:January 16, 2018   Accepted:January 22, 2018      Published Online:May 17, 2018
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DOI:doi:10.3969/j.issn.1007-7545.2018.06.004
KeyWord:primary crystallization temperature; molten salt; differential thermal analysis; Fe3O4
           
AuthorInstitution
zhanglisheng 华北理工大学
LiHui 华北理工大学
ZHANG Han-xin 华北理工大学
LIANG Jing-long 华北理工大学
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Abstract:
      Primary crystallization temperature of NaCl-KCl-NaF-Fe3O4 molten salt system was studied by differential thermal analysis. Effect of content of Fe3O4 and NaF on liquidus temperature of NaCl-KCl-NaF-Fe3O4 molten salt system was investigated. XRD and thermodynamic analysis of molten salt were carried out. The results show that Fe3O4 is physically dissolved in molten salt system. In XNaCl︰XKCl︰XNaF=3︰3︰4, when XFe3O4﹤30%, liquidus temperature of the system drops with increase of Fe3O4 content. Liquidus temperature of NaCl-KCl-NaF-Fe3O4 molten salt system rises with increase of NaF molar content.
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