Behavior of Sphalerite in Oxidative Ammonia Leaching Process
Received:April 29, 2018   Revised:May 02, 2018   Accepted:May 03, 2018      Published Online:August 20, 2018
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DOI:doi:10.3969/j.issn.1007-7545.2018.09.002
KeyWord:sphalerite; oxidative ammonia leaching; NH3-(NH4)2SO4 system; Na2S2O8; BaO2
           
AuthorInstitution
HUANG Ya-ling 中南大学 化学化工学院
YIN Zhou-lan 中南大学 化学化工学院
DING Zhi-ying 中南大学 化学化工学院
LIU Chun-xia 中南大学 化学化工学院
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Abstract:
      In NH3-(NH4)2SO4 system, effect of oxidants (Na2S2O8 and BaO2) on leaching behavior of sphalerite was studied by ammonia oxidation leaching process. The results show that zinc leaching rate is 28.4% and 82% respectively with Na2S2O8 and BaO2 as oxidant under the conditions including temperature of 110 ℃, total NH3 concentration of 4.00 mol/L, [NH3]/[NH4 ]=5/3, agitation speed of 500 r/min, L/S of 25, particle size of 0.063 mm, and leaching time of 4 h.
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