Process Study on Treatment of Silver Electrolysis Solution with EMEW
Received:May 24, 2018   Revised:May 24, 2018   Accepted:May 28, 2018      Published Online:September 19, 2018
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DOI:doi:10.3969/j.issn.1007-7545.2018.10.012
KeyWord:EMEW; silver electrolysis; neutralization
                    
AuthorInstitution
CHEN Hang 厦门紫金矿冶技术有限公司 福建
Lin Hong-fu 低品位难处理黄金资源综合利用国家重点实验室
ZHONG Shuiping 厦门紫金矿冶技术有限公司 福建
WANG Jun-e 厦门紫金矿冶技术有限公司 福建
WU Xinglin 铜绿色生产及伴生资源综合利用福建省重点实验室 福建
ZHANG Huanran 铜绿色生产及伴生资源综合利用福建省重点实验室 福建
LI Tao 铜绿色生产及伴生资源综合利用福建省重点实验室 福建
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Abstract:
      To address big consumption of copper powder, process backlog, and reduce production capacity of Caldor Furnaces during copper powder replacement process of silver electrolysis solution, novel process of “EMWE- neutralization precipitation” was proposed. After two-stage EMWE, concentration of silver ions in electrolyte drops from 83 g/L to 2.8 g/L, copper ion concentration remains unchanged at about of 14 g/L, and purity of electrodeposited silver powder is 99.9% above. Crude silver powder can be returned to process of sliver electrolyte preparation. After neutralization treatment, tail solution can be directly delivered to environmental protection workshop, and neutralization residue can be returned to anode mud acid leaching process.
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