Removal of Uranium from Aqueous Solution by Steel Slag Loaded with Hydroxyapatite
Received:October 14, 2018   Revised:October 17, 2018   Accepted:October 22, 2018      Published Online:December 21, 2018
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DOI:doi:10.3969/j.issn.1007-7545.2019.01.015
KeyWord:steel slag loaded with hydroxyapatite; uranium (Ⅵ); removal rate; adsorption capacity
                       
AuthorInstitution
Mo jing yi 东华理工大学
zhang wei min 东华理工大学
guo ya dan 东华理工大学
QIAN Cheng 东华理工大学
QIN Hai fu 东华理工大学
YANG Tian zi 东华理工大学
ZAN Jin jing 东华理工大学
ZENG hua 东华理工大学
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Abstract:
      Composite material of steel slag loaded with hydroxyapatite was prepared by sol-gel method with steel slag as carrier. Effects of pH value, adsorbent dosage, reaction time and initial uranium concentration on adsorption of U(VI) in aqueous solution were investigated by static test. The results show that this material has better removal property of U(VI). The results show that removal rate of U (VI) in aqueous solution with initial concentration of 5 mg/L is nearly 100% with adsorption capacity of 1.25 mg/g under the conditions of pH=4, dosage of 0.4 g and reaction time of 120 min. Adsorption process of U(VI) on composite is chemical adsorption which is more in line with quasi-second-order kinetic model (R2=0.996 9). Langmuir adsorption isotherm model (R2=0.999 1) shows that adsorption process is monolayer adsorption on surface of adsorbent, and the RL (RL<0.063) calculation shows that adsorption of U (VI) on composite is very close to irreversible adsorption.
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