Study on Arsenic Removal with Oxidative Acid Leaching and Stabilization of Arsenic-bearing Material
Received:March 02, 2019   Revised:March 05, 2019   Accepted:March 07, 2019      Published Online:June 17, 2019
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DOI:doi:10.3969/j.issn.1007-7545.2019.07.002
KeyWord:high-arsenic content metallurgical wastes; oxidative acid leaching; ferric arsenate; stabilization
                             
AuthorInstitution
FANG Xiong 中南大学化学化工学院
TANG XinCun 中南大学化学化工学院
WANG Yang 中南大学化学化工学院
HUANG Jie 中南大学化学化工学院
CHEN Xi 中南大学化学化工学院
RONG ZhiHao 中南大学化学化工学院
WU LiPing 中南大学化学化工学院
HUANG LiuChun 中南大学化学化工学院
LI Xin 中南大学化学化工学院
DANG Wei 中南大学化学化工学院
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Abstract:
      Oxidative acid leaching technology was applied to treat high-arsenic content metallurgical wastes. The results show that arsenic in solid residues falls to 1% or less under the conditions including sulfuric acid concentration of 1 mol/L, L/S=4/1, 20 ℃, and reaction time of 4 h. The filtrate with high-arsenic is pretreated by reduced iron powder before ferric arsenate with good crystal shape is synthesized by oxidation of ferrous sulfate solution. The arsenic-containing material meets SPLP leaching toxicity test and can be disposed safely.
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