Study on Recovery and Purification of Tantalum from Tantalum-Enrichment Slag
Received:April 12, 2019   Revised:April 16, 2019   Accepted:April 17, 2019      Published Online:August 16, 2019
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DOI:doi:10.3969/j.issn.1007-7545.2019.09.014
KeyWord:tantalum-enrichment slag; leaching; MIBK; extraction
                 
AuthorInstitution
XU Wan-xiang 西安瑞鑫科金属材料有限责任公司
LI Bo 西安瑞鑫科金属材料有限责任公司
WANG Jing-kun 西安瑞鑫科金属材料有限责任公司
LI Jin 西安瑞鑫科金属材料有限责任公司
ZHOU Yan 西安瑞鑫科金属材料有限责任公司
GUO Rui 西安瑞鑫科金属材料有限责任公司
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Abstract:
      Leaching and extraction of tantalum-enrichment slag were conducted. The results show that tantalum leaching rate is 99% above under the leaching conditions including leaching agent of 65%HF, temperature of 60 ℃, leaching time of 1 h, and L/S=4/1. Extraction rate of Ta, Hf, Ti, W in MIBK-HF-H2SO4 system is 86%, 1.6%, 0.2% and 5.8%, respectively, under the conditions including mass concentration of tantalum of 25 g/L, extraction time of 3 min, sulfuric acid concentration of 2.5 mol/L, and O/A=1/2. Separation of tantalum from mixed solution of hafnium, titanium, and tungsten is realized.
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