Study on Nano-TiO2 Modified LiNi0.83Co0.11Mn0.06O2 Cathode Material
Received:June 25, 2019   Revised:June 28, 2019   Accepted:July 01, 2019      Published Online:October 23, 2019
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DOI:doi:10.3969/j.issn.1007-7545.2019.11.014
KeyWord:controlled crystallization precipitation method; [Ni0.83Co0.11Mn0.06](OH)2; LiNi0.83Co0.11Mn0.06O2; doping modification
        
AuthorInstitution
ZHANG Chen 广东佳纳能源科技有限公司
ZHENG Jiang -feng 广东佳纳能源科技有限公司
TANG Pan 广东佳纳能源科技有限公司
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Abstract:
      [Ni0.83Co0.11Mn0.06](OH)2 precursor was firstly synthesized by coprecipitation method, and LiNi0.83Co0.11Mn0.06O2 cathode material was formed by two-stage sintering process in pure oxygen atmosphere. Ti4+ ion doping was achieved by adding nano-TiO2 in sintering process of precursor. Li[Ni0.83Co0.11Mn0.06]0.98Ti0.02O2 cathode shows an initial capacity of 185.6 mAh/g at current density of 1 C, and a capacity of 178.8 mAh/g can be obtained after 100 cycles, which corresponding retention ratio is up to 96.33%.
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