Leaching of Cobalt from Anode Powder of Waste Lithium Battery
Received:November 27, 2019   Revised:November 29, 2019   Accepted:December 03, 2019      Published Online:April 18, 2020
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DOI:doi:10.3969/j.issn.1007-7545.2020.05.005
KeyWord:lithium battery; LiCoO2; cathode; leaching
           
AuthorInstitution
gong qinxue 湖南邦普循环科技有限公司
liu yongqi 湖南邦普循环科技有限公司
wang du 湖南邦普循环科技有限公司
zheng yu 湖南邦普循环科技有限公司
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Abstract:
      In view of recovery of Co in anode plate of waste LiCoO2 battery, leaching of LiCoO2 under the conditions of H2SO4 and H2SO4+H2O2 was studied with crushed LiCoO2 anode material as raw material. The results show that leaching of LiCoO2 with H2SO4+H2O2 is better than that of H2SO4 alone. Under the condition of H2O2 reduction leaching, leaching rate of Co is 95% above under the conditions including reaction temperature of 80 ℃, L/S=6, initial sulfuric acid concentration of 250 g/L, dosage of hydrogen peroxide of 3%, and reaction time of 120 min. SEM analysis results show that LiCoO2 has been completely decomposed.
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