Classification Collection of Lead in Waste Paste of Positive and Negative Plate of Waste Lead-acid Battery
Received:February 17, 2020  Revised:February 19, 2020
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DOI:doi:10.3969/j.issn.1007-7545.2020.09.006
KeyWord:classification collection; acid leaching; waste lead paste
              
AuthorInstitution
LIU Heng-yi 广西大学 资源环境与材料学院 南宁
HUANG Kui 广西大学 资源环境与材料学院 南宁
HUANG Quan-li 广西大学 资源环境与材料学院 南宁
DONG Hai-li 广西大学 资源环境与材料学院 南宁
HUANG Chao-ran 广西大学 资源环境与材料学院 南宁
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Abstract:
      Lead in waste lead paste was recovered classifiably with acid leaching, i.e., positive electrode was leached by acid in heating condition, and negative electrode was directly leached with acid. The results show that anode paste is fully reacted for 24 h with sulfuric acid of mass fraction of 85%(L/S=108 g/L), and conversion rate of PbSO4 is 91.34%. Positive paste material is treated with mass fraction of sulfuric acid of 85%(L/S=108 g/L) for 2 h at 65 ℃, and conversion rate of PbSO4 is 95.69%. Recovered PbSO4 can be used directly after electrolysis or desulfurization crystallization by sodium hydroxide.
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