Study on Regeneration Process of Sodium Alkali Desulfurization Solution
Received:March 16, 2020   Revised:March 21, 2020   Accepted:March 24, 2020      Published Online:June 20, 2020
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DOI:doi:10.3969/j.issn.1007-7545.2020.07.018
KeyWord:membrane electrolysis; sodium alkali desulfurization solution; regeneration
        
AuthorInstitution
ZHANG Zheng-yang 矿冶科技集团有限公司
WANG Hai-bei 矿冶科技集团有限公司
SUN Liu-gen 矿冶科技集团有限公司
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Abstract:
      Sodium alkali desulfurization solution was regenerated by three compartment double cation membrane electrolysis. Effects of current density, total concentration of sodium alkali desulfurizer, pH value of sodium alkali desulfurization solution, electrolysis time, and electrolysis temperature on regeneration process were investigated. The results show that pH value of solution at outlet of cathode chamber and intermediate chamber is 6.72 and 1.65 respectively, current efficiency of sodium ion migration is 85.3%, and unit power consumption is 0.168 kWh/kg under the optimum conditions including current density of 127.8 A/m2, total concentration of sodium alkali desulfurizer of 50 g/L, pH value of sodium alkali desulfurization solution of 5.4, electrolysis time of 4 h, and electrolyte temperature of 60 ℃.
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