Enhanced Leaching of Complex Phase of Iron from Residue of Zinc Pressure Leaching and Its Dissolution Kinetics
Received:May 15, 2020   Revised:May 20, 2020   Accepted:May 22, 2020      Published Online:August 17, 2020
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DOI:doi:10.3969/j.issn.1007-7545.2020.09.003
KeyWord:zinc pressure-leaching residue; complex phase of iron; recovery of valuable metal; sulfuric roasting; kinetics
           
AuthorInstitution
GAO Wen-cheng 有研资源环境技术研究院(北京)有限公司
WANG Zhen-yin 有研资源环境技术研究院(北京)有限公司
WEN Jian-kang 有研资源环境技术研究院(北京)有限公司
CAI Liu-lu 有研资源环境技术研究院(北京)有限公司
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Abstract:
      Leaching rate of iron is in a low level due to existence of complex phase of iron during zinc pressure leaching. There are still some amount of iron in residue of zinc pressure leaching. Taking the residue from Guangdong province as research object, mineral liberation analysis is carried out at first. Then, sulfuric roasting combined with solution leaching was proposed to enhance decomposition and dissolution of complex phase of iron. Leaching rate of Fe and Zn is 83.31% and 97.06% respectively under the optimum conditions including temperature of 300 ℃, mass ratio of H2SO4 to residue of 0.4, roasting time of 2.0 h, leaching time of 1.0 h, and leaching temperature of 25 ℃, and L/S=5/1. Finally, leaching kinetics of roasting residue is successfully modeled by chemical reaction model with apparent activity energy of 23.18 kJ/mol, and semiempirical kinetics equation is obtained.
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