Study on Hydrometallurgical Desulfurization for Pressure Leaching Residue from Copper Smelting Dust
Received:August 17, 2021   Revised:September 03, 2021   Accepted:September 06, 2021      Published Online:November 19, 2021
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DOI:doi:10.3969/j.issn.1007-7545.2021.12.016
KeyWord:copper smelting; flue dust; pressure oxidation leaching; leach residue; desulfurization
                          
AuthorInstitution
GUO Dong-dong 武汉科技大学钢铁冶金及资源利用教育部重点实验室
QIN Qing-wei 武汉科技大学钢铁冶金及资源利用教育部重点实验室
SHEN Hong-hai 湖北大江环保科技股份有限公司
CHEN Rong-sheng 湖北大江环保科技股份有限公司
WANG Ming-xi 湖北大江环保科技股份有限公司
TANG Hai-bo 湖北大江环保科技股份有限公司
ZENG Su-qin 湖北大江环保科技股份有限公司
FENG Jin-ting 武汉科技大学 钢铁冶金及资源利用教育部重点实验室
XU Wen-jun 湖北大江环保科技股份有限公司
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Abstract:
      Clean utilization of copper smelting dust is always one of the themes of copper metallurgy. Pressure leaching technology of copper smelting dust can effectively achieve the purpose of comprehensive utilization. Hydrometallurgical desulfurization and electrolytic deposition of leaching residue are of great significance to eliminate emission of lead dust and lead vapor. Sodium carbonate was used as desulfurizer to carry out experiment of carbonate conversion desulfurization and pyrometallurgical processes. Effects of operation parameters on desulfurization rates were investigated, and the optimum operation conditions were determined. After ultrasonic treatment, particle size of d0.5 drops from 22.36 μm to 10.88 μm, d0.9 drops from 101.06 μm to 72.58 μm, and particle specific surface area rises from 13.24 m2/g to 15.89 m2/g. Desulfurization rate of leach residue rises from 76.61% to 85.52%. The results of oxygen-rich side blown bath smelting tests show that direct recovery of lead rises from 77.13% (leach residue) to 89.13% (desulfurized residue), and direct recovery of copper rises from 69.21% (leach residue) to 82.50% (desulfurized residue).
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