Static Infiltration Process of Phenolic Resin Based Carbon Material for Aluminum Electrolysis
Received:November 19, 2021   Revised:November 28, 2021   Accepted:November 29, 2021      Published Online:March 15, 2022
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DOI:doi:10.3969/j.issn.1007-7545.2022.04.007
KeyWord:aluminum electrolysis; carbon material; phenolic resin; aggregate; static wettability
                    
AuthorInstitution
LIU Meng-nan 贵州师范大学材料与建筑工程学院
LI Xiao-qing 贵州师范大学材料与建筑工程学院
ZHOU Jun 贵州师范大学材料与建筑工程学院
YAO Zhen 贵州师范大学材料与建筑工程学院
PENG Qian 贵州师范大学材料与建筑工程学院
LI Bin 贵州师范大学材料与建筑工程学院
LIU Wei 贵州师范大学材料与建筑工程学院
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Abstract:
      Electric calcined anthracite and pitch coke were selected as aggregates to study effects of process parameters and raw material properties on static wettability of phenolic resin and carbon aggregate. Surface functional groups and elemental occurrence forms of phenolic resin and carbon aggregate were analyzed by FT-IR and XPS. The results show that static wettability of phenolic resin to electric calcined anthracite and pitch coke rises with the increase of aggregate size, heating temperature and heating time, and rises first and drops latter with the increase of vibration times. Wettability of phenolic resin on electric calcined anthracite is affected by chemical composition, crystal structure and rheological properties of raw materials. The spread and diffusion of phenolic resin on carbon aggregate surface depends on interaction of surface functional groups including hydrogen bond, electrostatic bond, and acid-base neutralization reaction.
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