Study on Alkali Melting Roasting and Water Leaching of Cemented Carbide Grinding Waste in Sodium Carbonate System
Received:March 16, 2022   Revised:March 23, 2022   Accepted:March 31, 2022      Published Online:June 17, 2022
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DOI:doi:10.3969/j.issn.1007-7545.2022.07.012
KeyWord:waste cemented carbide;alkali melting roasting;grinding waste;water leaching
              
AuthorInstitution
HE Shan-ming 江西理工大学材料冶金化学学部
PAN Jie-chang 江西理工大学材料冶金化学学部
LI Wen-jun 江西理工大学材料冶金化学学部
XU Guo-zuan 崇义章源钨业股份有限公司
CHEN Bang-ming 崇义章源钨业股份有限公司
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Abstract:
      Cemented carbide grinding waste was treated by sodium carbonate alkali melting roasting and water leaching. Effects of roasting temperature, alkali dosage, roasting time, and water leaching parameters on WC conversion were systematically investigated. Under the optimum conditions of alkali melting roasting and water leaching, leaching rate of WO3 is 98% above, and the tungsten components in grinding waste can be transformed into crude sodium tungstate solution in one step. Increasing roasting temperature and alkali dosage can effectively improve leaching rate of WO3. Through adjusting pH value of crude sodium tungstate solution to 9—11, the concentration of impurities such as Cu, Cr and SiO2 in solution can be reduced.
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