Synthesis and Denitrification Performance of CeOx-MnOx/TiO2 Catalysts for Low Temperature SCR
Received:August 21, 2022   Revised:October 04, 2022   Accepted:October 08, 2022      Published Online:November 14, 2022
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DOI:doi:10.3969/j.issn.1007-7545.2022.12.013
KeyWord:catalyst; denitrification; selective catalytic reduction; low temperature; MnOx; CeOx
     
AuthorInstitution
TONG Zhen-song 矿冶科技集团有限公司
ZHAO Zhi-long 矿冶科技集团有限公司
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Abstract:
      The MnOx/TiO2 and CeOx-MnOx/TiO2 catalysts for low temperature selective catalytic reduction (SCR) denitrification were synthesized by ultrasonic impregnation method and characterized by SEM, EDS, BET and XPS. On this basis, the low-temperature SCR denitrification performances of the catalysts were studied, and effects of Mn loading amount and Ce/Mn molar ratio on the catalyst performance were investigated. The results show that when Mn loading amount is 15%, the catalyst has high catalytic activity. The doping of Ce is beneficial to improvement of catalytic activity of the catalyst. When Ce/Mn is 0.8, the catalyst has the highest catalytic activity, which reaches 97.86% at 180 ℃. Ce doping is beneficial to improve the sulfur and water resistance of the catalyst, but it still needs to be further improved.
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