Recovery and Purification of Wasted Washing Solution from Antimony and Arsenic Contaminated Soil by Stepwise Continuous Precipitation Method
Received:March 27, 2023   Revised:April 04, 2023   Accepted:April 06, 2023      Published Online:July 10, 2023
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DOI:doi:10.3969/j.issn.1007-7545.2023.08.020
KeyWord:antimony-arsenic contaminated soil; soil washing; wasted washing solution; oxalic acid recovery
                          
AuthorInstitution
WANG Jin-wen 广西博世科环保科技股份有限公司
CAO Fei-shu 广西博世科环保科技股份有限公司
TANG Wan-peng 广西博世科环保科技股份有限公司
XIE Dong-yan 广西博世科环保科技股份有限公司
YAN De-peng 广西博世科环保科技股份有限公司
CHEN Jian-ping 广西博世科环保科技股份有限公司
CHEN Jun-xian 广西博世科环保科技股份有限公司
LIU Song-hao 广西博世科环保科技股份有限公司
LIN Hong-fei 广西博世科环保科技股份有限公司
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Abstract:
      Stepwise continuous precipitation method was applied to recover and purify the wasted oxalic acid (OA) solution from washing process of high concentration of Sb and As soil. The results show that OA recovery rate from wasted washing solution is 35.54% when the pH value is controlled at 1.4, and the washing efficiencies of recycled OA solution on Sb and As contaminated soil is 38.39% and 55.54%, respectively. When the pH value rises to 8—9, the removal rate of Sb and As in the waste solution is more than 99%. At the same time, the leaching toxicity of heavy metals such as Cd, As and Sb in sediment produced during the process is all lower than the relevant concentrations in the “Identification Standards for Hazardous Wastes-Identification for Extraction Toxicity” (GB 5085.3—2007). Therefore, the stepwise continuous precipitation method can recover OA from wasted washing solution, and reduce the cost and environmental risks of soil washing technology. Thus, this study provides a theoretical reference for the recovery and purification of wasted soil washing solution.
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