Treatment of Waste Ternary Lithium Ion Cathode Materials by Carbon Reduction Roasting - Water Leaching Method
Received:April 12, 2023   Revised:April 19, 2023   Accepted:April 23, 2023      Published Online:July 10, 2023
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DOI:doi:10.3969/j.issn.1007-7545.2023.08.004
KeyWord:spent ternary Li-ion battery; ternary positive electrode powder; carbon reduction roasting; water leaching; lithium
     
AuthorInstitution
ZHOU Wen-jun 北京矿冶研究总院
JIANG Xun-xiong 北京矿冶研究总院
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Abstract:
      The method of carbon reduction roasting - water leaching was used for selective extraction of Li from waste ternary Li-ion cathode materials. Through thermodynamic analysis, combined with XRD, ICP and other detection means, the effects of roasting temperature, roasting time and carbon content on Li leaching rate were studied. The results show that Li in ternary Li-ion anode material could be preferentially extracted by carbon reduction roasting - water leaching method. Li in calcine exists as Li2CO3. The leaching rate of Li is 97.85% under the conditions including roasting temperature of 750 ℃, roasting time of 1 h, and carbon dosage of 20%, and the preferential selective extraction of Li is achieved.
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