Recovery and Reuse of Waste Ternary Lithium Battery Cathode Materials
Received:May 24, 2023   Revised:May 31, 2023   Accepted:June 05, 2023      Published Online:September 04, 2023
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DOI:doi:10.3969/j.issn.1007-7545.2023.10.015
KeyWord:waste lithium batteries; carbon thermal reduction; leaching; high temperature solid phase roasting; recycled ternary materials
                 
AuthorInstitution
WEI Lin 广西大学资源环境与材料学院
HUANG Kui 广西大学资源环境与材料学院;广西高校环境保护重点实验室
XIONG Hao 广西大学资源环境与材料学院
JIANG Yuxin 广西大学资源环境与材料学院
DONG Haili 广西大学资源环境与材料学院;广西高校环境保护重点实验室
HUANG Guoliang 广西大学资源环境与材料学院
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Abstract:
      The closed-loop recovery process of selective recovery of Li and Ni, Co, Mn and reuse was achieved by carbon thermal reduction, water leaching, and high temperature solid phase roasting applying waste ternary lithium battery cathode material as the research object. Li leaching rate is 91.04% under the optimal conditions including roasting temperature of 650 ℃, roasting time of 2 h, carbon addition of 10%, leaching time of 1 h, and solid-liquid ratio of 30 g/L. The leaching solution can be recycled three times to increase the Li concentration from 1.01 g/L to 2.68 g/L. Li2CO3 is prepared by evaporation crystallization of the leaching solution. The leaching residue which mainly composed of Ni, Co, and MnO, is roasted in air atmosphere to prepare a ternary precursor. Then Li2CO3 and ternary precursors are mixed and grinded for roasting to obtain a regenerated ternary material.
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