Pb Control Technology for Large Plate High Current Density Zinc Electrodeposition
Received:June 06, 2023   Revised:June 16, 2023   Accepted:June 19, 2023      Published Online:October 09, 2023
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DOI:doi:10.3969/j.issn.1007-7545.2023.11.003
KeyWord:large plate high current density; zinc electrodeposition; complex high germanium containing raw materials; zinc sheet contains Pb; overvoltage; dendritic zinc
           
AuthorInstitution
LAN Guohui 云南驰宏锌锗股份有限公司
FU Guang 云南驰宏锌锗股份有限公司
WU Fang 云南驰宏锌锗股份有限公司
CHEN Bo 云南驰宏锌锗股份有限公司
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Abstract:
      The actual production phenomenon of high current density zinc electrodeposition of 3.2 m2 large plate with complex high germanium material was analyzed. The influences of electrolyte clarity, impurity content in electrolyte, distribution of Pb in the electrolyte flow process, and current density on Pb content in zinc sheet Pb were studied. Based on the exploration and analysis, a series of measures were taken to reduce the lead content in zinc sheets, mainly from the aspects of inhibiting the dissolution rate of lead in anode plates and improving the settling effect of lead in electrolyte. The research and practice of zinc sheet Pb control technology can provide reference for the industry.
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