Influence of Slag Composition on Thermal Conductivity and Precipitated Phase Structure of Zinc Smelting Slag Treated by Side-Blown Smelting
Received:August 22, 2023   Revised:August 27, 2023   Accepted:September 04, 2023      Published Online:November 30, 2023
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DOI:doi:10.3969/j.issn.1007-7545.2024.01.001
KeyWord:side-blown smelting furnace; slag composition; thermal conductivity; slag crust; water-cooled slag-hanging
                          
AuthorInstitution
WANG He 西安建筑科技大学冶金工程学院
ZHAO Junxue 西安建筑科技大学冶金工程学院
CAO Geng 西安建筑科技大学冶金工程学院
LI Bin 西安建筑科技大学冶金工程学院
WANG Ze 西安建筑科技大学冶金工程学院
WANG Zhengmin 汉中锌业有限责任公司
CUI Yaru 西安建筑科技大学冶金工程学院
KANG Yi 西安建筑科技大学冶金工程学院
GUO Lixin 汉中锌业有限责任公司
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Abstract:
      When the side-blown smelting furnace adopts water-cooled slag-hanging furnace wall, the slag with high thermal conductivity can form a stable slag shell on the surface of the furnace lining to protect and prolong the service life of the furnace lining. Aiming at FeO-CaO-SiO2-PbO-ZnO five-element slag system used for treating jarosite residue and lead-silver slag, the thermal conductivity of furnace slag crust was measured by steady-state plate method, and the microstructure of solid slag crust was analyzed by SEM to explore the influence of slag composition change on thermal conductivity and crystalline mineral phase of slag crust. The results show that adding CaO and SiO2 will increase the thermal conductivity of slag crust, especially the addition of CaO has the most significant effect on slag type. The thermal conductivity of the optimized slag type rises to 17.94 W/(m?K), which is 135% higher than that of the original slag. The phase precipitated at high temperature during the condensation process is melilite, and its melting point and viscosity are significantly lower than that of the original slag. The adjusted slag type is easier to form a stable slag crust, which is beneficial to water cooling and slag hanging to protect the furnace.
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